Don't get any ASUS sound card (including anything in the Xonar line). I've owned a couple and each one is a driver nightmare. The ASUS offical drivers are garbage, and the custom drivers (unified drivers) still don't fix a lot of the issues.
I've tried virtually every configuration of drivers and settings (including shared vs exclusive) and my system BSODs constantly with ASIO and WASAPI when outputting 24/96 (Win7 64, Memtest checks out fine, all drivers updated, very lean custom-built system). If you plan on only using DirectSound, then the Xonars are fine, but if you want bit-perfect streaming, they are incredibly unreliable. There are many, many pages of these comments if you run google seaches on Xonar WASAPI bsod, crash, crashing, etc.
You might want to consider a USB DAC or a USB-S/PDIF converter solution. If you are set on having a sound card, if you are going to use ASIO, ASIO4ALL, or WASAPI, do not get an ASUS card--their drivers are terrible and their driver support is terrible. Creative is not much better though a lot of people like the e-mu line. The Auzentechs might be okay, but it all depends on your budget. If you're on a Windows machine, you want to avoid doing as much with your sound card or the Windows mixer as possible.
Edited by Elysian - 8/22/11 at 9:31am