Well that depends on your DAC, some are working supposedly better with USB and some with optical.
I am currently using my icon HDP at home with USB and my Fiio D3 with optical cables and the sound quality is so close, I doubt I could differentiate in a blind test.
But there is one huge advantage in using optical: there is no electric connection between your audio gear and the MacBookPro, that makes a huge difference for some... no humming, buzzing, etc. with wrong grounding etc.