I know this is somewhat outdated, just posting if someone is curious (I actually stared very hard on my card to find out what those 5 ports do - I only use the headphone jack lol)
So this is from top to bottom:
Red - Analog Output Front Right - RCA - To AMP / Speaker.
White - Analog Output Front Left - RCA - To AMP / Speaker.
Black 1 - Analog Output 6.30mm jack *1 To Headphone
Black 2 - Analog Input line in 6.30mm jack *1 To Other source
Gray - Digital S/PDIF Output to DAC
Or check the manual :D
Also there is a new driver 7.12.8.1794 available, in case you are interested.
Manual and drivers can be obtained from the following link.
http://www.asus.com/Multimedia/Audio_Cards/Xonar_Essence_ST/#dwnload
*I have removed the wrong information about TCA jack being amplified*
Edited by OneSec - 9/5/11 at 7:40am