Quote:
Originally Posted by necropimp 
on commercial CDs the data is actually held in the plastic of the disc... the metal however creates the reflective surface and if it gets oxidized or damaged the laser doesn't get reflected back properly
i've never looked much into how CD-Rs work but the earliest CD-Rs i have still work just fine and the oldest commercial CDs i have are still good
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I think you have that backwards.
IIRC, commercially produced CDs have tiny pits etched in the metalized disc, and the plastic is just a holder for that disc.
In really old CDs the disc is sandwitched between two layers of polycarb - you can recognize these by the way the metal goes all the way to the outer and inner edges. My at-least-20-years-old copy of ChangesBowie is one of these.
In the more modern CDs, the plastic is just a tray. The disc is dropped into it and sealed in with essentially glue. This is why it's easier to destroy a CD from the label side than the data side.
I could be wrong - maybe they do etch the plastic rather than the disc. In any case, the metalized disc is critical to the function of the media.
In CD-R (and DVD-R, etc) there is a dye in the plastic that undergoes a change in opacity when exposed to laser light, or left out in the sun for a long time.
In CD-RW the plastic undergoes a phase change that alters it's opacity, and this can be reversed.
I think the danger from the sun with manufactured discs is probably mostly heat causing delamination. With CD-R the sun is literally degrading the data.
As for the lifespan, it's going to vary with use and abuse, but professional archivists turn over media every 2-3 years. just in case.