Beezar's a good place to shop. Tom's a great guy, he'll get you fitted up.
Bypassing with tiny caps is a technique used to pass higher frequencies through the signal path more easily. There are loads of comments regarding the Wimas and Vitamin Qs in the
Millett MAX thread. From what I can remember, the Wimas are pretty heavy on the bass while the Vitamin Qs have very good neutrality, but that's when the caps are used in a completely different context. If you're wondering about bypass capacitors in general, Google can get you some good reading material. Try these articles:
BypassingThe Basics - Bypass Capacitorshttp://focus.ti.com/lit/an/scba007a/scba007a.pdf
And as per usual, sound is very unique to each system. The same component will sound different in a different part of the system, eg. source, amp, and in different parts within that piece of equipment, eg. power supply, signal path. If you're lucky, you may get similar results, but from what I know, the larger capacitor will dominate the sound characteristic over the bypass. Section 6.0.0 in the OP will give you a bit more reading material regarding choosing capacitors.
Where will you be putting these capacitors? Size becomes an issue along with the capacitance.