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Musings on silver-plated copper

post #1 of 2
Thread Starter 
I'm thinking of making myself a new power cord for my headphone amp (for the look as much as anything), and was doing some reading on the different wire available. I ran across several people recommending silver-plated copper (mil-spec) wire.

This got me thinking. Silver is slightly more conductive than copper, but so is fatter copper. Silver plating will only give a very small difference in conductivity unless the frequency is high enough to give a significant skin effect, which certainly isn't the case for power cables. So how can anyone hear a difference from silver plating?

One possible answer occurred to me while contemplating the name "mil-spec". The main purpose of silver-plated copper is actually to provide corrosion resistance in hazardous area, like chemical plants or military applications. I also discovered another interesting fact - teflon insulated wire is always silver-plated to protect it from the corrosive chemicals used in the teflon-coating process.

My theory then is that the (apparently) audible differences from silver-plated copper actually come from the different dielectric properties of the teflon insulation rather than the increased conductivity of the silver. Certainly for low frequencies anyway, and I reckon it applies to audio frequencies too (depending on your religious persuasion with regards to the skin effect)

Anyone got other theories?

[And yes, I know I probably won't hear any difference from my new power cord but at the least it will look pretty].
post #2 of 2
Nice theory, but not complete I think.

Quote:
teflon insulated wire is always silver-plated to protect it from the corrosive chemicals used in the teflon-coating process
Not true, take f.i Nordost Flatline or kimber 8TC, tefloncoated copper.

Silverplating is supposed to do good things to copper; the cables surface gets smoother and silveroxide is about as conductive as silver, so the cables prperties won't chance so much over time.
Adversaries of silverplated copper (like me) complain about it sounding bright, and not at all like pure silver.
Reasons I've heart but cannot judge to be correct are:
- the lower a frequency the bigger the amplitude and the deper the signal enters the cable; so it's frequncy dependent weher the signal is copletely carried by the silver or also partly by the copper, which has a different conductivity. This give an audible distortion where the crossover is.
- the copper under the silver slightly oxidates, and there is a kind of capacitor created.
Again I do not know if this is right.

I completely agree the material of the isolator has an influence on the SQ, teflon to my ears sounding more detailed and dynamic then f.i. PVC.
(I once compared some Kimbercables that had the same copper insdide but different isoaltors)
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